Title of article
A Unique Chelating Effect of Sc(OTf)3 to Organofluorine Compounds
Author/Authors
Hiyama، Tamejiro نويسنده , , Kajiro، Hiroshi نويسنده , , Mori، Atsunori نويسنده , , Nishihara، Yasushi نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-458
From page
459
To page
0
Abstract
The scandium trifluoromethanesulfonate-catalyzed cleavage of acetate bearing two or three fluorine atoms at a position (beta) to an acetoxy group proceeds exceptionally rapidly. The high efficiency of the hydrolysis is caused by a chelating effect of scandium with the fluorine atoms and an acetate moiety.
Keywords
Bibliometrics , productivity rankings , refereed journals , research in probability and statistics
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
28035
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