• Title of article

    Post-Metallocenes: A New Bis(salicylaldiminato) Zirconium Complex for Ethylene Polymerization

  • Author/Authors

    Matsui، Shigekazu نويسنده , , Mitani، Makoto نويسنده , , Saito، Junji نويسنده , , Tanaka، Hidetsugu نويسنده , , Makio، Haruyuki نويسنده , , Fujita، Terunori نويسنده , , Tohi، Yasushi نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1999
  • Pages
    -1262
  • From page
    1263
  • To page
    0
  • Abstract
    A new bis(salicylaldiminato) zirconium complex was synthesized and its structure determined by X-ray analysis. This complex displayed an exceptionally high ethylene polymerization activity of 519 kg-PE/mmol-Zr·h using methylaluminoxane (MAO) as a cocatalyst. In contrast, by using Ph3C+B-(C6F5)4 / iBu3Al as a cocatalyst, the complex furnished polyethylene of exceptionally high molecular weight (Mv; 505 × 10^4).
  • Keywords
    Goodness of fit , Identifiability , Model diagnosis , Parametric bootstrap , Restricted latent class models
  • Journal title
    CHEMISTRY LETTERS
  • Serial Year
    1999
  • Journal title
    CHEMISTRY LETTERS
  • Record number

    28132