Title of article :
Insertion of Phenylacetylene into cis-Silyl(stannyl)platinum Complexes
Author/Authors :
Sagawa، Takashi نويسنده , , Katayama، Hiroyuki نويسنده , , Ozawa، Fumiyuki نويسنده , , Sakamoto، Yasunobu نويسنده , , Tanaka، Rika نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 1999
Abstract :
Silyl(stannyl)platinum(II) complexes cis-Pt(SiR3)(SnMe3)(PMe2Ph)2 (SiR3 = SiMe3, SiMe2Ph, SiMePh2, SiPh3) undergo insertion of phenylacetylene into the Pt–Si or Pt–Sn bond. The site selectivity dramatically varies with silyl ligands under kinetic conditions, while under thermodynamic conditions the insertion into the Pt–Si bond exclusively takes place irrespective of silyl ligands.
Keywords :
Goodness of fit , Model diagnosis , Parametric bootstrap , Restricted latent class models , Identifiability
Journal title :
CHEMISTRY LETTERS
Journal title :
CHEMISTRY LETTERS
