Title of article
Strong Basic Sites Accelerate the Deactivation of Oxide Catalysts Supported on FSM-16 for the Vapor-Phase Beckmann Rearrangement of Cyclohexanone Oxime
Author/Authors
Nakajima، Tsuyoshi نويسنده , , Mishima، Shozi نويسنده , , Shouro، Daisuke نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-1318
From page
1319
To page
0
Abstract
The acidic and basic properties of FSM-16-supported Al2O3, ZnO or CdO were determined by the temperature-programmed desorption (TPD) of ethylamine. Relationship of the deactivation rate of the catalyst during the vapor-phase Beckmann rearrangement with the acidic and basic properties was studied. It was found that the deactivation was accelerated with an increase in the amount of the strong basic sites.
Keywords
Identifiability , Model diagnosis , Goodness of fit , Parametric bootstrap , Restricted latent class models
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
28244
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