A Highly Effective and Practical Biaryl Synthesis with Triallyl(aryl)silanes and Aryl Chlorides

A general and convenient approach for the palladium-catalyzed cross-coupling of triallyl(aryl)silanes, stable and easily accessible arylsilanes, with aryl chlorides has been demonstrated. The scope of the reaction is broad and a wide variety of functional groups are tolerant to the present catalyst system.