Title of article
Alkoxyhydrosilanes as Sources of Silylene Ligands: Novel Approaches to Transition Metal–Silylene Complexes
Author/Authors
Tobita، Hiromi نويسنده , , Sato، Takahiro نويسنده , , Okazaki، Masaaki نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
-867
From page
868
To page
0
Abstract
Irradiation of Fe(CO)5 and HSiMe2OR (R = alkyl or aryl group) together with hexamethylphosphoric triamide (HMPA) produces (CO)4Fe=SiMe2·HMPA and SiMe2(OR)2. Even in the absence of HMPA, irradiation of Fe(CO)5 and HSiMe2O(2-C5H4N) affords (CO)3(H)Fe{SiMe2···O(2-C5H4N)···SiMe2}. In these reactions, the alkoxyhydrosilanes act as sources of the silylene ligand.
Keywords
prediction , Power requirement , Genetic-fuzzy system , Application-production research , grinding , Surface finish
Journal title
CHEMISTRY LETTERS
Serial Year
2004
Journal title
CHEMISTRY LETTERS
Record number
28592
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