Title of article
Unprecedented Sequential Deprotonation of Ruthenium–Aqua Framework Affording Ruthenium–Oxo–Dithiolene Complex
Author/Authors
Sato، Kazunobu نويسنده , , Takui، Takeji نويسنده , , Tanaka، Koji نويسنده , , Sugimoto، Hideki نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
-1081
From page
1082
To page
0
Abstract
A new type of aqua ruthenium–terpyridine complexes with dithiolenes (S2C2Ph2, S2C6H8) were synthesized. The pKa values were 3.8 and 7.0 for S2C2Ph2 complex and 6.5 for S2C6H8 one. The S2C2Ph2 complex gives the corresponding oxo one by the sequential deprotonation, whereas the S2C6H8 complex is just converted to the hydroxo one.
Keywords
Application-production research , Genetic-fuzzy system , prediction , Surface finish , Power requirement , grinding
Journal title
CHEMISTRY LETTERS
Serial Year
2004
Journal title
CHEMISTRY LETTERS
Record number
28701
Link To Document