Title of article
A Novel Enantioselective Reaction. Palladium-catalyzed Enantiodistinctive Reaction of Bicyclic Allylic Compounds
Author/Authors
Shimizu، Isao نويسنده , , Daimon، Hisashi نويسنده , , Ogawa، Ryohei نويسنده , , Itagaki، Shuichi نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
-1221
From page
1222
To page
0
Abstract
Reaction of ((plus-minus))-2(beta)-acetoxy-4a(beta)-methyl-2,3,4,4a,5,6,7,8-octahydronaphthalene (4) with dimethyl malonate anion in the presence of a catalytic amount of [(1-Me-allyl)PdCl]2 and (S)-(-)-BINAP proceeded enantiodistinctively to give both the nucleophilic substituted product (2S,4aS)-5 and the diene (R)-6 as the elimination product in considerable enantiomeric excesses.
Keywords
prediction , grinding , Genetic-fuzzy system , Power requirement , Surface finish , Application-production research
Journal title
CHEMISTRY LETTERS
Serial Year
2004
Journal title
CHEMISTRY LETTERS
Record number
28771
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