Title of article :
Photochemical Generation of Halo(silyl)silylene: Spectroscopic Observation and Reactivity
Author/Authors :
Ichinohe، Masaaki نويسنده , , Sekiguchi، Akira نويسنده , , Tanaka، Takashi نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Abstract :
Dihalobis(tri-tert-butylsilyl)silanes (t-Bu3Si)2SiX2 (1a: X = Cl, 1b: X = Br) underwent photochemically (alpha)-elimination to produce halo(tri-tert-butylsilyl)silylenes, which were successively trapped by carbon tetrachloride, triethylsilane, and 3-hexyne. The halo (tri-tert-butylsily)silylenes were observed by UV–vis spectroscopy in a 3-methylpentane matrix at 77 K.
Keywords :
Genetic-fuzzy system , prediction , Surface finish , Power requirement , Application-production research , grinding
Journal title :
CHEMISTRY LETTERS
Journal title :
CHEMISTRY LETTERS
