Title of article
Rotational spectrum, dynamics and bond energy of 2,5-dihydrofuran-krypton van der Waals complex
Author/Authors
Velino، Biagio نويسنده , , Melandri، Sonia نويسنده , , Maris، Assimo نويسنده , , Favero، Paolo G. نويسنده , , Caminati، Walther نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
-1918
From page
1919
To page
0
Abstract
The equilibrium conformation, dynamics and dissociation energy of the weakly bonded 2,5-dihydrofuran-Kr complex have been deduced from its free jet millimetre-wave spectrum. The equilibrium distance of Kr with respect to the centre of mass of the molecule is 3.61 ?, with Kr tilted 12.8o from the perpendicular to the centre of mass of the ring towards the oxygen atom. The dissociation energy is estimated from the centrifugal distortion constant DJ to be about 3.5kJ mol-1.
Keywords
Organic compounds , Infrared spectroscopy , Electronic paramagnetic resonance (EPR) , Chemical synthesis , Fullerenes
Journal title
MOLECULAR PHYSICS
Serial Year
2000
Journal title
MOLECULAR PHYSICS
Record number
42163
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