Combined DSC and Pulse-Heating Measurements of Electrical Resistivity and Enthalpy of Tungsten, Niobium, and Titanium

Measurements of thermophysical properties such as enthalpy, electrical resistivity, and specific heat capacity as a function of temperature starting from the solid state into the liquid phase for W, Nb, and Ti are preseInted in this work. An ohmic pulse-heating technique allows measurements of enthalpy and electrical resistivity from room temperature to the end of the stable liquid phase within 60μs. The simultaneous optical measurement of temperature is limited by the fast pyrometers with an onset temperature of Tmin = 1200–1500 K; below these temperatures, the fast pyrometers are not sensitive. A differential scanning calorimeter (DSC) is used for determination of the specific heat capacity, and also to obtain enthalpy values in the temperature range of 600–1700 K. Combining the two methods eIntends the range of values of electrical resistivity and enthalpy versus temperature down to 600 K. Results on the metals W, Nb, and Ti are reported and compared to literature values. This paper is a continuation of earlier work.