Title of article :
Equation of State for Substances that Satisfy the Corresponding States Law
Author/Authors :
V. S. Vorob’ev ، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Universal expressions for the free energy of substances that satisfy the law of
corresponding states are obtained. The equation of state is constructed using
an iInterpolation between the high temperature Debye approximation and the
ideal-gas one. Missing data needed for calculations have been found from
the comparison of calculated and tabulated values of entropy and pressure
along the phase coexistence curves. The thermodynamics of corresponding
states, constructed in this way, allows one to find the triple- and criticalpoint
parameters, as well as the phase coexistence curves with an accuracy
that does not exceed the accuracy of the law of corresponding states itself.
Keywords :
triplepoint. , Equation of state , corresponding state law , Critical point
Journal title :
International Journal of Thermophysics
Journal title :
International Journal of Thermophysics