Title of article :
New handy relationship between the conductivity of concentrated nonaqueous electrolyte solutions and the dielectric constant and viscosity of the solvents
Author/Authors :
Guillaume Herlem، نويسنده , , Pierre Tran-Van، نويسنده , , Pascal Marque، نويسنده , , Sébastien Fantini، نويسنده , , Jean-François Penneau، نويسنده , , Bernard Fahys، نويسنده , , Michel Herlem and Henri Perez، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
For nonaqueous electrolyte solutions, we correlated the equivalent conductance Λ0 at infinite dilution and the conductivity maximum κMAX with only two intrinsic parameters of the pure solvents: the dielectric constant and the viscosity. On the basis of two new handy empirical formulas, predictions of Λ0 and κMAX can now be made for a given salt in any solvent on the basis of only one Λ0 or κMAX measurement in only one solvent.
Keywords :
Dielectric constant , Concentrated nonaqueous electrolytes , Conductivity maximum , Limiting conductance at infinite dilution , viscosity
Journal title :
Journal of Power Sources
Journal title :
Journal of Power Sources