Title of article
Two molybdenum (VI) monophosphates with a tunnel structure: AMoO2PO4 (A=Cs, Tl) and structural relationships in the series
Author/Authors
Raveau، B. نويسنده , , Leclaire، A. نويسنده , , Guesdon، A. نويسنده , , Borel، M. M. نويسنده , , Berrah، F. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
-876
From page
877
To page
0
Abstract
Two new molybdenum (VI) monophosphates CsMoO2PO4 and TlMoO2PO4 have been synthesized by solid state chemistry. Their structure were determined from single crystal X-ray diffraction studies. The frameworks MoO2PO4 delimit tunnels in which are located the univalent cations. Structural relationships between the different monophosphates of the AMoO2PO4 series with A = Ag, Na, K, Tl, Cs, are presented in which two kinds of frameworks appear owing to the size of the univalent cations.
Keywords
Organic sulfate , Infrared spectrometry , chemical preparation , thermal behavior , crystal structure
Journal title
Solid State Sciences
Serial Year
2001
Journal title
Solid State Sciences
Record number
46351
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