Abstract :
Two novel double flexible spacers brideged biscalix[4]arenes 25,25ʹ,27,27ʹ-bis(1,3dioxypropane)-bis(5,11,17,23-p-tert-tetrabutylcalix[4]arene-26,28-diol) (1) and 25,25ʹ,27,27ʹ-bis(1,4-dioxybutane)-bis(5,11,17,23-p-tert-tetrabutylcalix[4]arene-26,28diol) (2) have been evaluated as cesium ion-selective ionophore in polymeric membrane electrodes. The electrodes all give the good Nernstian response of 51 mV per decade for Cs+ in the concentration range from 1×10-1 to 1×10-5 M and good selectivity. The potentiometric selectivity of Cs+-ISEs based on 1 and 2 for cesium ion over other alkali metal ions, alkaline-earth metal ions and NH4+ have been assessed. Effects of membrane composition and pH on the response of Cs+-ISEs based on 1 and 2 were also discussed.
