Title of article :
Prediction of the thermodynamic properties for the Ga–Sb–Pb ternary system
Author/Authors :
Dragan Manasijevic، نويسنده , , Dragana Zivkovic، نويسنده , , Zivan Zivkovic، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The results of some thermodynamic prediction methods applied to the Ga–Sb–Pb ternary system are presented in this paper. The Chou general solution model and the traditional models of Kohler and Toop were included in the calculation for the comparison and discussion. Integral enthalpy of mixing and integral excess Gibbs energy dependences on composition for the 15 investigated cross sections at 973 K and 1073 K, respectively, were obtained according to the applied models. The comparison between the results of the three models shows good mutual agreement. Obtained results were used for the further calculation of partial molar quantities for every component of the investigated ternary system. Calculated activity values at 1073 K for all components are given in the form of isoactivity diagrams.
Keywords :
Ga–Sb–Pb system , General solution model , Toop model , Kohler model , Thermodynamics of alloys
Journal title :
C A L P H A D (Computer Coupling of Phase Diagrams and Thermochemistry)
Journal title :
C A L P H A D (Computer Coupling of Phase Diagrams and Thermochemistry)