Evaluation of the suitability of various γ lines for the γ spectrometric determination of 238U in environmental samples

γ-ray spectrometry is extensively used for 238U determination because of its simplicity in terms of sample preparation. Nevertheless, processing of measurement data presents several challenges, such as evaluation of overlapping photopeaks and calibration of detector efficiencies for different matrices and photon emissions. Besides, the emission probability data for 238U and its daughters show significant discrepancies among different studies. In this study, we assess the suitability of four methods, using the photopeaks at 63.3, 92.6, 766.4 and 1001.0 keV, respectively, to determine 238U in environmental samples. With that aim we analyse several reference and environmental samples, detailing the entire procedure involved in the calculation of the 238U activities and highlighting possible error sources. Based on the results obtained, we propose new yields for the 234Th photons and compare these to corresponding values from the literature.