Influence of changes of platinum electrode surface condition on the kinetics of the oxidation of sodium dithionite and sulfite in alkaline solution

The influence of the surface condition of a platinum electrode on the kinetics of the electrochemical oxidation of sodium dithionite and sulfite was investigated. It was found that the oxidation of sulfite does only occur at platinum oxide while the oxidation of dithionite takes place at platinum oxide as well as at platinum hydroxide and bare platinum. However, dithionite cannot be oxidised at rearranged platinum hydroxide, which is formed during the reduction of platinum oxide, a process that is strongly dependent on the applied anodic vertex potential. For both substances a hysteresis effect was observed between forward and backward scan but in both cases the effects could be explained considering the platinum surface condition. As well in the absence as in the present of sulfite and/or dithionite reproducible current-potential curve were obtained after cycling three times between the applied vertex potentials. The observed difference between the first and subsequent scans again could be explained when the variation of the platinum surface condition as a function of potential and number of cycles was taken into consideration.