Excess Oxygen in LaMnO3+DELTA

The chemical stability of the layered Li1-xCoO2 and Li1-xNi0.85CoO .15O2 cathodes is compared by monitoring the oxygen content with lithium content (1-x) in chemically delithiated samples. The Li1-xCoO2 system tends to lose oxygen from the lattice at deep lithium extraction while the Li1-xNi0.85Co0.15O2 system does not lose oxygen at least for (1-x)>0.3. This difference seems to result in a lower reversible (practical) capacity (140 mA h/g) for LiCoO2 compared to that for LiNi0.85Co0.15O2 (180 Ma h/g). The loss of significant amount of oxygen leads to a sliding of oxide layers and the formation of a major P3 and a minor O1 phase for the end member CoO2- with =0.33. In contrast, Ni0.85Co0.15O2- with a small amount of =0.1 maintains the initial O3 layer structure.