Phosphinooxazolines as assembling ligands in heterometallic complexes

It is shown that phosphinooxazolines such as (2-oxazoline-2-ylmethyl)diphenylphosphine 1 can be used as P,N assembling ligands for the synthesis of heterometallic complexes. These were obtained in a stepwise manner from the iron carbonyl complexes containing one, [Fe(CO)4 (PCH2-oxazoline-P)]2, or two, trans-[Fe(CO)3(PCH2-oxazoline-P)2]6, P-bound phosphinooxazoline ligands. These metalloligands were then reacted with metal complexes. With 2, complete ligand transfer from Fe to the second metal (Pd) was sometimes observed. The metal-metal bonded complex [(OC)4Fe(mu-PCH2-oxazoline-P,N)PdCl2]3 was of limited stability, whereas the trinuclear complex trans-[{(OC)4Fe(µ-PCH2oxazoline-P,N)}2CoCl2]4, in which 2 functions as a N-donor metalloligand toward the tetrahedral Co(II) centre, was stable and could be fully characterised by X-ray diffraction. This complex catalyses the oligomerization of ethylene to give linear -olefins in the range C4-C26, with a maximum of the Schulz-Flory distribution around C6. The complex [{(OC)4Fe(mu-PCH2-oxazoline-P,N)}2HgI2]5 was also prepared from 6. With the metalloligand 6, the FePd and FeCo metal-metal bonded compounds trans-[(OC)3Fe(mu-PCH2-oxazoline-P,N)2Pd(NCMe)](BF4)28 and trans-[(OC) 3Fe(mu-PCH2-oxazoline-P,N)2CoCl2]9 were obtained.