Title of article :
Replacement of [RuH2(PMe3)4] by [RuH2(PEt3)4] switches reaction products: synthesis of fluoride-bridged diruthenium complexes
Author/Authors :
Archibald، Stephen J. نويسنده , , Jasim، Naseralla A. نويسنده , , Perutz، Robin N. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The fluoride-bridged ruthenium dimers [Ru2(µ-F)3(PR3)6][F(HF)n] (R = Et, Pr, Bu; n(almost equal) 3) were synthesised by the reactions of the cis-[RuH2(PR3)4] complexes with NEt3·3HF in THF; the crystal structure of [Ru2(µ-F)3(PEt3)6]OTf, formed by subsequent reaction with NH4OTf, reveals Ru-F distances in the range 2.132(2)-2.170(2) (angstrom) and Ru-F-Ru angles in the range 91.72(7)93.02(7)°.
Keywords :
Abamectin compatibility , IPM , Biological control , Greenhouse , Liriomyza trifolii , DIGLYPHUS ISAEA
Journal title :
DALTON TRANSACTIONS
Journal title :
DALTON TRANSACTIONS
