• Title of article

    Rational Design of Molecular Sheets Composed of Interconnecting Eight- and Twenty-Four-Membered Rings: Use of Lithiated Aggregates To Control Network Assembly

  • Author/Authors

    Henderson، Kenneth W. نويسنده , , Kennedy، Alan R. نويسنده , , Macdonald، Lynn نويسنده , , MacDougall، Dugald J. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -2838
  • From page
    2839
  • To page
    0
  • Abstract
    The lithiated (organo)sulfonylacetonitrile complex [MeSO2CHCNLi THF] (3) has been prepared and structurally characterized in order to demonstrate that well-known molecular aggregates of s-block metals may be used as building blocks in the controlled assembly of complex supramolecular architectures. The solid state structure of 3 can be described as a novel basket-weaved, 2-D network, composed of (SO2Li)2 "dimeric" rings joined via "interdimer" donation of nitrile units.
  • Journal title
    INORGANIC CHEMISTRY
  • Serial Year
    2003
  • Journal title
    INORGANIC CHEMISTRY
  • Record number

    66200