Title of article
Rational Design of Molecular Sheets Composed of Interconnecting Eight- and Twenty-Four-Membered Rings: Use of Lithiated Aggregates To Control Network Assembly
Author/Authors
Henderson، Kenneth W. نويسنده , , Kennedy، Alan R. نويسنده , , Macdonald، Lynn نويسنده , , MacDougall، Dugald J. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2838
From page
2839
To page
0
Abstract
The lithiated (organo)sulfonylacetonitrile complex [MeSO2CHCNLi THF] (3) has been prepared and structurally characterized in order to demonstrate that well-known molecular aggregates of s-block metals may be used as building blocks in the controlled assembly of complex supramolecular architectures. The solid state structure of 3 can be described as a novel basket-weaved, 2-D network, composed of (SO2Li)2 "dimeric" rings joined via "interdimer" donation of nitrile units.
Journal title
INORGANIC CHEMISTRY
Serial Year
2003
Journal title
INORGANIC CHEMISTRY
Record number
66200
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