Author/Authors :
Zhao، Hong نويسنده , , Xue، Ziling نويسنده , , You، Xiao-Zeng نويسنده , , Abrahams، Brendan F. نويسنده , , Qu، Zhi-Rong نويسنده , , Wang، Xi-Sen نويسنده , , Li، Yong-Hua نويسنده , , Song، Yu-Mei نويسنده , , Liu، Yu-juan نويسنده , , Ye، Qiong نويسنده , , Xiong، Ren-Gen نويسنده ,
Abstract :
The reactions of (S)-3-cyanophenylalanine with NaN3 in the presence of H2O and Lewis acids (ZnCl2 and CdCl2) afford two unprecedented 3D homochiral networks, mono[(S)-5-(3-tetrazoyl)phenylalaninato]zinc(II) (1) and mono[(S)-5-(3-tetrazoyl)-phenylalaninato]cadmium(II) monoaqua(II) (2), respectively. The two compounds are isostructural with noninterpenetrated SrAl2 topology. The structure of these coordination polymers gives new insight into Sharplessʹ reaction of chiral 5-substituted 1H-tetrazole and homochiral supramolecular array constructions.
Keywords :
Verticillium wilt , meristem culture , certification , peppermint , spearmint , Mentha
