Catalytic Asymmetric Sulfoxidation by Chiral Manganese Complexes: Acetylacetonate Anions as Chirality Switches

Long-chain polymer-assisted growth of one-dimensional (1D) nanostructures has been investigated in previous research. This kind mild method has lots of merits such as not requiring complex procedures, without template supporting etc. Can the short-chain polymer also be used to grow long nanowires? In the present work, a shortchain polymer (PEG400) was found to promote the formation of 1D ZnO nanostructures, which cannot be obtained by long-chain polymers (such as PEG10000). Moreover, nanowires and nanorods can be selectively synthesized by using short-chain polymers. The influence factors for the formation of 1 D ZnO nanostructures were also investigated in detail. The XRD, Raman spectrum, XPS, SEM, TEM, ED, HRTEM, EDXA, and PL spectra have been provided for the characterization of the as-obtained nanowires and nanorods.