Title of article
An Unusual Zinc-Promoted Decomposition of a Bis(2-{pyrid-2-yl}ethyl)amine Derivative
Author/Authors
Halcrow، Malcolm A. نويسنده , , Barrett، Simon A. نويسنده , , Kilner، Colin A. نويسنده , , Mokuolu، Q. Folshade نويسنده , , McGowan، Patrick C. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-4135
From page
4136
To page
0
Abstract
The complex [ZnBr2L1] (L1 = ferrocenylmethyl-bis[2-{pyrid-2-yl}ethyl]amine) contains bidentate L1 by crystallography and NMR spectroscopy and decomposes during recrystallization from CH2Cl2/pentane via both C-N bond cleavage and formation steps. Other [MBr2L1] (M = Co, Ni, Cu) compounds do not undergo this reaction and contain L1 bound in the more usual tridentate coordination mode.
Keywords
Harmonic , magnetic
Journal title
INORGANIC CHEMISTRY
Serial Year
2005
Journal title
INORGANIC CHEMISTRY
Record number
66514
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