• Title of article

    An Unusual Zinc-Promoted Decomposition of a Bis(2-{pyrid-2-yl}ethyl)amine Derivative

  • Author/Authors

    Halcrow، Malcolm A. نويسنده , , Barrett، Simon A. نويسنده , , Kilner، Colin A. نويسنده , , Mokuolu، Q. Folshade نويسنده , , McGowan، Patrick C. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    -4135
  • From page
    4136
  • To page
    0
  • Abstract
    The complex [ZnBr2L1] (L1 = ferrocenylmethyl-bis[2-{pyrid-2-yl}ethyl]amine) contains bidentate L1 by crystallography and NMR spectroscopy and decomposes during recrystallization from CH2Cl2/pentane via both C-N bond cleavage and formation steps. Other [MBr2L1] (M = Co, Ni, Cu) compounds do not undergo this reaction and contain L1 bound in the more usual tridentate coordination mode.
  • Keywords
    Harmonic , magnetic
  • Journal title
    INORGANIC CHEMISTRY
  • Serial Year
    2005
  • Journal title
    INORGANIC CHEMISTRY
  • Record number

    66514