Author/Authors :
Güdel، Hans U. نويسنده , , Wernsdorfer، Wolfgang نويسنده , , Stoeckli-Evans، Helen نويسنده , , Neels، Antonia نويسنده , , Sieber، Andreas نويسنده , , Boskovic، Colette نويسنده , , Bircher، Roland نويسنده , , Waldmann، Oliver نويسنده , , Ochsenbein، Stefan T. نويسنده , , Chaboussant، Gregory نويسنده , , Kirchner، Nadeschda نويسنده , , Slageren، Joris van نويسنده , , Janssen، Stefan نويسنده , , Juranyi، Fanni نويسنده , , Mutka، Hannu نويسنده ,
Abstract :
A new family of tetranuclear Ni complexes [Ni4(ROH)4L4] (H2L = salicylidene-2-ethanolamine; R = Me (1) or Et (2)) has been synthesized and studied. Complexes 1 and 2 possess a [Ni4O4] core comprising a distorted cubane arrangement. Magnetic susceptibility and inelastic neutron scattering studies indicate a combination of ferromagnetic and antiferromagnetic pairwise exchange interactions between the four NiII centers, resulting in an S = 4 spin ground state. Magnetization measurements reveal an easy-axis-type magnetic anisotropy with D (almost equal)-0.93 cm6^-1 for both complexes. Despite the large magnetic anisotropy, no slow relaxation of the magnetization is observed down to 40 mK. To determine the origin of the low-temperature magnetic behavior, the magnetic anisotropy of complex 1 was probed in detail using inelastic neutron scattering and frequency domain magnetic resonance spectroscopy. The spectroscopic studies confirm the easy-axis-type anisotropy and indicate strong transverse interactions. These lead to rapid quantum tunneling of the magnetization, explaining the unexpected absence of slow magnetization relaxation for complex 1.
