Preparation and Operating Conditions for Cobalt Cerium Oxide Catalysts Used in the Conversion of Synthesis Gas into Light Olefins

Cobalt cerium oxides, prepared using a co-precipitation procedure, were studied as catalysts for the conversion of synthesis gas to light olefins (C2-C4). Specifically, we studied the effect of a range of preparation variables, including the molar ratio of the [Co]/[Ce] of the precipitation solution, ageing time and calcination temperature. In addition, the effects of supports and promoters on the catalysts’ activity and selectivity and a range of reaction temperatures using synthesis gas with different H2/CO molar feed ratios were investigated. The catalyst containing a molar ratio of 80% Co and 20% Ce, aged for 2 h, supported with 15 wt% SiO2 without any promoter, at an operating temperature of 450 ºC and an H2/CO feed ratio of 2/1 (GHSV = 4500 h-1), performed optimally for the conversion of synthesis gas to light olefins. The characterization of both the precursors and the calcined catalysts by powder X-ray diffraction, scanning electron microscopy, Brunauer-Emmett-Teller specific surface area measurements and thermal analysis methods, including TGA and DSC, show that all the preparation variables influenced the catalyst precursor structure