Title of article :
Metal Complexes with 2,3-Bis(diphenylphosphino)-1,4-diazadiene Ligands: Synthesis, Structures, and an Intramolecular MetalMediated [4 + 2] Cycloaddition Employing a Benzene Ring as a Dienophile
Author/Authors :
Vaughan، Gavin نويسنده , , Walther، Dirk نويسنده , , Liesicke، Stefan نويسنده , , B?ttcher، Lars نويسنده , , Fischer، Reinald نويسنده , , G?rls، Helmar نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
stereochemistry , Triorganylstannyl , EWG , Neopentyl , Nitroalkanes , Nitrogen Nucleophiles , Oxygen , (alpha)Carbon , Cycloalkyl Halides , Phosphorus Nucleophiles , Sulfur Nucleophiles , sp2 Carbons , Cumyl , Nitrobenzyl , Photostimulated Reactions , Geminal Dihalides , sp3 Carbons , Heterocyclic Analogues , Radicals Intermediates , Trihalides , Carbanions , Regiochemistry , Alicyclic Aliphatic Substrates , Aliphatic Substrates , Carbonylation
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY
