Title of article :
Molecular Motions in the Solid State: the Thermochromic Nitro-Nitrito Interconversion in Nickel(II) Bis(diamine) Complexes
Author/Authors :
Fabbrizzi، Luigi نويسنده , , Licchelli، Maurizio نويسنده , , Poggi، Antonio نويسنده , , Zema، Michele نويسنده , , Hortal?، Marta Ansa نويسنده , , Foti، Francesco نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
sp3 Carbons , Heterocyclic Analogues , (alpha)Carbon , Cycloalkyl Halides , Radicals Intermediates , Trihalides , Aliphatic Substrates , Carbonylation , Oxygen , Regiochemistry , Alicyclic Aliphatic Substrates , Nitrobenzyl , Phosphorus Nucleophiles , sp2 Carbons , Cumyl , Sulfur Nucleophiles , EWG , Neopentyl , Photostimulated Reactions , Geminal Dihalides , Nitrogen Nucleophiles , Nitroalkanes , Carbanions , stereochemistry , Triorganylstannyl
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY