Title of article :
Century-Known Copper Salt Cu(OAc)(OMe) Proven To Be a Unique Magnetic Lattice Composed of Tetranuclear Copper(II) Species with a Rare Binding Mode of the Acetate Anion
Author/Authors :
Reedijk، Jan نويسنده , , Roubeau، Olivier نويسنده , , Spek، Anthony L. نويسنده , , Koval، Iryna A. نويسنده , , Gamez، Patrick نويسنده , , Lutz، Martin نويسنده , , Driessen، Willem L. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
Regiochemistry , Alicyclic Aliphatic Substrates , stereochemistry , Triorganylstannyl , EWG , Neopentyl , Nitrobenzyl , Oxygen , Phosphorus Nucleophiles , sp2 Carbons , Cumyl , Photostimulated Reactions , Geminal Dihalides , Carbanions , sp3 Carbons , Heterocyclic Analogues , Nitroalkanes , Aliphatic Substrates , Carbonylation , (alpha)Carbon , Cycloalkyl Halides , Radicals Intermediates , Trihalides , Nitrogen Nucleophiles , Sulfur Nucleophiles
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY
