Title of article :
31P NMR Spectroscopy as a Powerful Tool for the Determination of Enantiomeric Excess and Absolute Configurations of (alpha)-Amino Acids
Author/Authors :
Bravo، Judith نويسنده , , Cativiela، Carlos نويسنده , , Chaves، Julio E. نويسنده , , Navarro، Rafael نويسنده , , Urriolabeitia، Esteban P. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
Phosphorus Nucleophiles , Nitrobenzyl , sp2 Carbons , Cumyl , sp3 Carbons , Heterocyclic Analogues , Photostimulated Reactions , Geminal Dihalides , Radicals Intermediates , Trihalides , Regiochemistry , Alicyclic Aliphatic Substrates , Aliphatic Substrates , Carbonylation , EWG , Neopentyl , stereochemistry , Triorganylstannyl , Nitroalkanes , (alpha)Carbon , Cycloalkyl Halides , Carbanions , Nitrogen Nucleophiles , Sulfur Nucleophiles , Oxygen
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY