Title of article :
Synthesis, Crystal Structure, and Characterization of the First Nb3 Triangular Cluster Compound Bonded to Fluorine Ligands: Association of Nb3I^(i)F^(i)3F^(a)8L^(a) Units and Nb^(IV)L6 Octahedra with L = O and F
Author/Authors :
Hernandez، O. نويسنده , , CORDIER، S. نويسنده , , PERRIN، C. نويسنده , , Thépot، J.-Y. نويسنده , , Shames، A. I. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
Aliphatic Substrates , Carbonylation , stereochemistry , Triorganylstannyl , EWG , Neopentyl , (alpha)Carbon , Cycloalkyl Halides , Nitrogen Nucleophiles , Carbanions , Oxygen , Sulfur Nucleophiles , Phosphorus Nucleophiles , Nitrobenzyl , sp2 Carbons , Cumyl , Photostimulated Reactions , Geminal Dihalides , Radicals Intermediates , Trihalides , sp3 Carbons , Heterocyclic Analogues , Nitroalkanes , Regiochemistry , Alicyclic Aliphatic Substrates
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY
