Title of article :
51V Solid-State Magic Angle Spinning NMR Spectroscopy and DFT Studies of Oxovanadium(V) Complexes Mimicking the Active Site of Vanadium Haloperoxidases
Author/Authors :
Rehder، Dieter نويسنده , , Pooransingh، Neela نويسنده , , Pomerantseva، Ekaterina نويسنده , , Ebel، Martin نويسنده , , Jantzen، Sven نويسنده , , Polenova، Tatyana نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2) and 2,5-bis(4-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(l) salts has been investigated. Four new coordination polymers were prepared by solution reactions and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. {[Ag(L2)]SO3CF3}n (1) (triclinic, PI; a = 10.1231(7) A, b = 13.9340-...
Keywords :
Oxygen , Nitrogen Nucleophiles , (alpha)Carbon , Cycloalkyl Halides , Sulfur Nucleophiles , Nitroalkanes , Radicals Intermediates , Trihalides , Nitrobenzyl , stereochemistry , Triorganylstannyl , Aliphatic Substrates , Carbonylation , EWG , Neopentyl , Photostimulated Reactions , Geminal Dihalides , Regiochemistry , Alicyclic Aliphatic Substrates , sp3 Carbons , Heterocyclic Analogues , Phosphorus Nucleophiles , sp2 Carbons , Cumyl , Carbanions
Journal title :
INORGANIC CHEMISTRY
Journal title :
INORGANIC CHEMISTRY
