Title of article
Ferromagnetism in a Dinuclear Nickel(II) Complex Containing Triethylenetetramine and Tricyanomethanide
Author/Authors
Fuess، Hartmut نويسنده , , Ehrenberg، Helmut نويسنده , , Boa، Roman نويسنده , , Gembicky، Milan نويسنده , , Herchel، Radovan نويسنده , , Haase، Wolfgang نويسنده , , Jager، Lothar نويسنده , , Wagner، Christoph نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-6964
From page
6965
To page
0
Abstract
Triethylenetetramine (L4) was used as a tetradentate blocking ligand that, after complexation with NiII, leaves two sites ready for ligation with tricyanomethanide. The formed binuclear complex [L4Ni(NCC(CN)CN)2NiL4](ClO4)2 exhibits a ferromagnetic coupling with J/hc = +0.15 cm^-1 and gNi = 2.126; below 16 K, a ferromagnetic ordering is evidenced by ac magnetic susceptibility (both in-phase and out-of-phase), magnetization, field-cooled magnetization, and zero-field-cooled magnetization measurements.
Keywords
molecular data , molecular processes , ISM: molecules
Journal title
INORGANIC CHEMISTRY
Serial Year
2003
Journal title
INORGANIC CHEMISTRY
Record number
67026
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