Title of article
77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2].Se8
Author/Authors
Massiot، P. Florian, D. نويسنده , , Fayon، F. نويسنده , , Goldbach، A. نويسنده , , Vosegaard، T. نويسنده , , Wachhold، M. نويسنده , , Kanatzidis، M. G. نويسنده , , Saboungi، M.-L. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-6995
From page
6996
To page
0
Abstract
The structure of Rb2[Pd(Se4)2].Se8 has been investigated using 87Rb magic angle spinning and static NMR and 77Se magic angle spinning NMR. The number and the integrated intensities of the 87Rb and 77Se resonances are in full agreement with the crystallographic structure of the compound. The 87Rb and 77Se nuclear spin interaction parameters have been used to characterize the main structural units of the compound: infinite [Rb(Se8)]xx+ columns and polymeric [Pd(Se4)2]x2x- sheet anions.
Keywords
ISM: molecules , molecular processes , molecular data
Journal title
INORGANIC CHEMISTRY
Serial Year
2003
Journal title
INORGANIC CHEMISTRY
Record number
67037
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