New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8((mu)4-O)4(phpz)8(thf)4]
Author/Authors :
Reedijk، Jan نويسنده , , Spek، Anthony L. نويسنده , , Aromi، Guillem نويسنده , , Kooijman، Huub نويسنده , , Tanase، Stéfania نويسنده , , Bouwman، Elisabeth نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Pages :
-3146
From page :
3147
To page :
0
Abstract :
Reaction of Mn(ClO4)2·6H2O with 3(5)-methyl-5(3)-(2-hydroxyphenyl)pyrazole (H2phpz) affords a highly asymmetric octanuclear manganese(III) cluster resulting from the different bridging coordination modes of the ligand H2phpz.
