Title of article
Asymmetric electrochemical lactonization of diols on a chiral 1-azaspiro[5.5]undecane N-oxyl radical mediator-modified graphite felt electrode
Author/Authors
Anzai، Jun-ichi نويسنده , , Bobbitt، James M. نويسنده , , Kashiwagi، Yoshitomo نويسنده , , Kurashima، Futoshi نويسنده , , Chiba، Shinya نويسنده , , Osa، Tetsuo نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-113
From page
114
To page
0
Abstract
A graphite felt electrode modified with (6S,7R,10R)-4-amino-2,2,7-trimethyl-10-isopropyl-1-azaspiro[5.5]undecane N-oxyl was prepared for electrocatalytic oxidation of diols; electrolysis of diols on the modified electrode yielded optically active lactones (92.0–96.4%), with an enantiopurity of 82–99% ee.
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68163
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