• Title of article

    Highly efficient chiral metal cluster systems derived from Ru3(CO)12 and chiral diiminodiphosphines for the asymmetric transfer hydrogenation of ketones

  • Author/Authors

    Zhang، Hui نويسنده , , Nakamura، Hideaki نويسنده , , Yang، Chuan-Bo نويسنده , , Li، Yan-Yun نويسنده , , Donga، Zhen-Rong نويسنده , , Gao، Jing-Xing نويسنده , , Murata، Kunihiko نويسنده , , Ikariya، Takao نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -141
  • From page
    142
  • To page
    0
  • Abstract
    The chiral Ru cluster-based catalyst systems generated in situ from Ru3(CO)12 and chiral diiminodiphosphine tetradentate ligands effected asymmetric transfer hydrogenation of propiophenone in 2-propanol, leading to 1-phenyl-1-propanol in 94% yield and with 96% ee.
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    68205