Author/Authors :
Naimi-Jamal، Mohammad Reza نويسنده , , Mokhtari، Javad نويسنده Department of Chemistry, Iran University of Science and Technology, P.O. Box 16846-13114 Tehran, I.R. IRAN Mokhtari, Javad , Dekamin، Mohammad Gorban نويسنده Department of Chemistry, Iran University of Science and Technology, P.O. Box 16846-13114 Tehran, I.R. IRAN Dekamin, Mohammad Gorban , Javanshir، Shahrzad نويسنده Department of Chemistry, Iran University of Science and Technology, P.O. Box 16846-13114 Tehran, I.R. IRAN , , Hamzeali، Hamideh نويسنده Islamic Azad University, East Tehran Branch, I.R. IRAN ,
Abstract :
Effective methodologies for efficient preparation of semicarbazones from aldehydes or ketones via milling and the subsequent regeneration of the parent carbonyls by gaseous nitrogen dioxide are described under solid-solid and gas-solid reaction conditions, respectively. These methods are fast, simple and environmentally benign which do not require the use of any auxiliaries such as catalysts or solid supports in their procedures.