Title of article :
Electrochemical Investigation of Antibacterial Laser Dye Compound in 1,2-Dichloroethane at a Platinum Electrode
Author/Authors :
El-Hallag، Ibrahim Shibl نويسنده Chemistry Department, Faculty of Science, Tanta University, 31527, Tanta, EGYPT , , El-Mossalamy، Elsayed Hassan نويسنده Chemistry Department, Faculty of Science, King Abdul Aziz University, P.O. Box 80203, Jeddah 21589, SAUDI ARABIA , , Asiri، Abdullah Mohamed نويسنده ,
Issue Information :
فصلنامه با شماره پیاپی 63 سال 2012
Abstract :
Diolefinic antibacterial laser dye namely 1,4-Bis[2-(4-Pyridyl) Vinyl] Benzene (4PVB) have been investigated electrochemically using cyclic voltammetry, chronoamperometry, convolution and deconvolution voltammetry combined with digital simulation techniques
at a platinum electrode in 0.1 mol / L Tetra Butyl Ammonium Perchlorate (TBAP) in solvent
1,2-dichloroethane. The diolefinic species were reduced by consuming two sequential electrons
to form radical anion and dianion. The second electron transfer was followed by chemical step
i.e the electrode reaction proceed as EEC scheme. In scanning the potential to positive direction, the diolefinic laser dye compound was oxidized by loss of one electron, which was followed by a fast chemical process ( isomerization or association). The pathway of electrode reaction and
the electrochemical parameters of the investigated compound were discussed & determined using cyclic voltammetry and chronoamperometry techniques. The extracted electrochemical parameters
were verified and confirmed via digital simulation and convolutive voltammetry methods.
Journal title :
Iranian Journal of Chemistry and Chemical Engineering (IJCCE)
Journal title :
Iranian Journal of Chemistry and Chemical Engineering (IJCCE)