Title of article
A Simple and Effective Protocol for One-Pot Diazotization-Iodination of Aromatic Amines by Acidic Ionic Liquid [H-NMP]HSO4 at Room Temperature
Author/Authors
Hajipour ، Abdolreza نويسنده Pharmaceutical Research Laboratory, Faculty of Chemistry, Isfahan University of Technology, Isfahan, I.R. IRAN , , Mohammadsaleh، Fatemeh نويسنده Pharmaceutical Research Laboratory, Faculty of Chemistry, Isfahan University of Technology, Isfahan, I.R. IRAN ,
Issue Information
فصلنامه با شماره پیاپی 60 سال 2011
Pages
6
From page
23
To page
28
Abstract
A simple and efficient one-pot method for the preparation of aromatic iodides
has been developed by sequential diazotization–iodination of aromatic amines employing sodium nitrite and sodium iodide in the presence of acidic ionic liquid N-methyl-2-pyrrolidonum hydrosulfate ([H-NMP]HSO4). The diazonium salts that are formed by this ionic liquid are stable at room temperature and react rapidly with sodium iodide to produce aryl iodides in moderate to good yields. The mild reaction conditions, straightforward procedure, inexpensive and green method make these transformations superior to the reported
Journal title
Iranian Journal of Chemistry and Chemical Engineering (IJCCE)
Serial Year
2011
Journal title
Iranian Journal of Chemistry and Chemical Engineering (IJCCE)
Record number
682907
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