Title of article
High tetraalkylaluminate fluxionality in half-sandwich complexes of the trivalent rare-earth metals
Author/Authors
Anwander، Reiner نويسنده , , Klimpel، Michael G. نويسنده , , Dietrich، H. Martin نويسنده , , Shorokhov، Dmitry J. نويسنده , , Scherer، Wolfgang نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-1007
From page
1008
To page
0
Abstract
Steric factors govern the formation of half-sandwich complexes (C5Me4R)Ln[N(SiHMe2)2]2 according to acid–base reactions utilising Ln[N (SiHMe2)2]3(thf)2 and substituted cyclopentadienes. Subsequent trimethylaluminium-promoted silylamide elimination produces the first halfsandwich bis(tetramethylaluminate) complexes (C5Me4R)Ln(AlMe4)2.
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68436
Link To Document