• Title of article

    Insertion of organoindium carbenoids into rhodium halide bonds: revisiting a classic type of transition metal–group 13 metal bond formation

  • Author/Authors

    Fischer، Roland A. نويسنده , , Steinke، Tobias نويسنده , , Gemel، Christian نويسنده , , Cokoja، Mirza نويسنده , , Winter، Manuela نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -1065
  • From page
    1066
  • To page
    0
  • Abstract
    Insertion of the carbenoid group 13 metal species InCp*(Cp*= pentamethylcyclopentadienyl) and InC(SiMe3)3 into the Rh–Cl bonds of [{RhCp*Cl2}2] yields the new complexes [Cp*Rh(InCp*)3(Cl)2]1 and [Cp*Rh(mu2-Cl)2(InC(SiMe3)3)3]2, respectively, exhibiting novel cage-like intermetallic complexes with In–Cl–In bridges.
  • Keywords
    general linear group , unitary group , linear map
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    68460