Author/Authors :
Lewis، Nathan S. نويسنده , , Brunschwig، Bruce S. نويسنده , , Peters، Jonas C. نويسنده , , Hu، Xile نويسنده , , Cossairt، Brandi M. نويسنده ,
Abstract :
In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as –0.28 V vs. SCE.