Title of article :
Synthesis of novel axially chiral Rh–NHC complexes derived from BINAM and application in the enantioselective hydrosilylation of methyl ketones
Author/Authors :
Shi، Jian-Min نويسنده , , Duan، Wei-Liang نويسنده , , Rong، Guo-Bin نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1ʹ-binaphthalenyl-2,2ʹ-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The corresponding sec-alcohols can be obtained in high yields with good to excellent ee.
Keywords :
pth moment convergence , uniform norm , piecewise linear approximation , fractional Brownian motion , Maxima of Gaussian processes
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
