Title of article
An efficient recognition motif for an alkyl moiety in water
Author/Authors
Kitagawa، Susumu نويسنده , , Wada، Kenji نويسنده , , Mizutani، Tadashi نويسنده , , Kozake، Katsuyuki نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2917
From page
2918
To page
0
Abstract
The artificial receptor bearing decamethylene groups bridging the porphyrin framework and the hydrophilic poly(ethylene oxide) auxiliary groups showed incremental binding free energy of 3.5 kJ mol^–1 per CH2 for 4-alkylpyridines, demonstrating that an ideal hydrophobic environment for the recognition of an alkyl group is constructed in water.
Keywords
Maxima of Gaussian processes , uniform norm , pth moment convergence , piecewise linear approximation , fractional Brownian motion
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68649
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