Title of article :
An efficient recognition motif for an alkyl moiety in water
Author/Authors :
Kitagawa، Susumu نويسنده , , Wada، Kenji نويسنده , , Mizutani، Tadashi نويسنده , , Kozake، Katsuyuki نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The artificial receptor bearing decamethylene groups bridging the porphyrin framework and the hydrophilic poly(ethylene oxide) auxiliary groups showed incremental binding free energy of 3.5 kJ mol^–1 per CH2 for 4-alkylpyridines, demonstrating that an ideal hydrophobic environment for the recognition of an alkyl group is constructed in water.
Keywords :
Maxima of Gaussian processes , uniform norm , pth moment convergence , piecewise linear approximation , fractional Brownian motion
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
