Author/Authors :
Garcia-Granda، Santiago نويسنده , , Ruiz، Javier نويسنده , , Ceroni، Mario نويسنده , , Vivanco، Marilin نويسنده , , Gonzalo، Marta P. نويسنده , , Maelen، Francisco van der نويسنده ,
Abstract :
Oxidation of the thioketone residue in the complex [Mn(CO)4{(PPh2)2C=S}]+(2) with hydrogen peroxide affords the sulfonate derivative [Mn(CO)4{(PPh2)2C(H)SO3}](3), which shows amphoteric behaviour in reversible acid–base processes, and is easily chlorinated to give [Mn(CO)4{(PPh2)2C(Cl)SO3}](8).
