Title of article
Dehydropolymerization of arylsilanes catalyzed by a novel silylmolybdenum complex
Author/Authors
Ito، Takashi نويسنده , , Minato، Makoto نويسنده , , Matsumoto، Takaomi نويسنده , , Ichikawa، Miyuki نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2967
From page
2968
To page
0
Abstract
A complex [MoH3{Si(Ph)[Ph2PCH2CH2P(Ph)C6H4-o]2}](1) can act as single-component catalyst for dehydrogenative polymerization of ArSiH2R (Ar = Ph, p-tolyl, o-tolyl; R = H, Me) to (ArSiR)n: p- and o- tolylsilane produced the polymers of respectable molecular weights (Mw of 17300 and 6700 respectively) and polymerization of secondary silane, methylphenylsilane, gave a substantial molecular weight (Mw of 1750).
Keywords
Maxima of Gaussian processes , uniform norm , pth moment convergence , piecewise linear approximation , fractional Brownian motion
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68712
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