Title of article :
Encapsulation of paramagnetic 3d1-vanadium(IV) in an antiferromagnetically coupled dodecanuclear copper(II) cage
Author/Authors :
Nethaji، Munirathinam نويسنده , , Chakravarty، Akhil R. نويسنده , , Mukherjee، Arindam نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
A mixed metal cluster [Cu12VO5L6] of a pentadentate Schiff base (H3L) containing vanadium(IV) in a dodecanuclear copper(II) cage is prepared by vanadyl templated self assembly of dicopper(II) precursor and the structurally characterized complex shows antiferromagnetic coupling involving copper(II) centers, which leads close to diamagnetism for the Cu(II) cage below 40 K in the presence of an encapsulated paramagnetic 3d1-V(IV) atom.
Keywords :
uniform norm , pth moment convergence , piecewise linear approximation , Maxima of Gaussian processes , fractional Brownian motion
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
