Title of article :
Stereoselective synthesis of tetrahydropyran-3-ones by rearrangement of oxonium ylides generated from metal carbenoids
Author/Authors :
Clark، J. Stephen نويسنده , , Whitlock، Gavin نويسنده , , Jiang، Shende نويسنده , , Onyia، Ngozi نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The synthesis of tetrahydropyran-3-ones by copper-catalysed reactions of diazo ketone tethered allylic ethers has been explored. Product distribution can be explained by the intermediacy of a free ylide or direct rearrangement of a metal-bound ylide equivalent.
Keywords :
starburstinfrared , evolution galaxies
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
